Core-Shell Gold Nanorod@Layered Double Hydroxide Nanomaterial with Highly Efficient Photothermal Conversion and Its Application in Antibacterial and Tumor Therapy
单位：[1]State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering, College of Chemistry, Beijing University of Chemical Technology, North Third Ring Road 15, Chaoyang District, Beijing 100029, China[2]Department of Hepatobiliary Surgery, Department of Gastroenterology, China−Japan Friendship Hospital, 2 Yinghuayuan Dongjie, Beijing 100029, China[3]School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
Photothermal conversion efficiency (eta) of gold nanorods (GNRs) can be tuned by enlarging the aspect ratio and forming the core-shell structure. Herein, an easy synthesis method is developed to construct the core-shell GNR@LDH nanostructure with GNRs and layered double hydroxides (LDHs). The interaction between Au and LDHs results some electron deficiency on the surface of Au and the more electrons induce more thermal energy conversion. The eta value of GNR@LDH can reach up to 60% under the 808 nm laser irradiation, which is a significant enhanced conversion efficiency compared with the reported GNR-based photothermal therapy materials. CTAB (cetyltrimethyl ammonium bromide) can be replaced totally during the synthesis process, and GNRs maintain a good dispersion in LDHs. This core-shell composite GNR@LDH can be applied in photothermal, antibacterial, tumor therapy and biological imaging with low dosage and nontoxicity.
基金：
Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21575032, 81728010, 21775010, 11811530639]; Beijing Natural Science FoundationBeijing Natural Science Foundation [7192106]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [PT1902, XK1901, XK1802-6]; University of Chinese Academy of SciencesChinese Academy of Sciences
第一作者单位：[1]State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering, College of Chemistry, Beijing University of Chemical Technology, North Third Ring Road 15, Chaoyang District, Beijing 100029, China
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推荐引用方式(GB/T 7714)：
Ma Kun,Li Yawen,Wang Zhenguo,et al.Core-Shell Gold Nanorod@Layered Double Hydroxide Nanomaterial with Highly Efficient Photothermal Conversion and Its Application in Antibacterial and Tumor Therapy[J].ACS APPLIED MATERIALS & INTERFACES.2019,11(33):29630-29640.doi:10.1021/acsami.9b10373.
APA：
Ma, Kun,Li, Yawen,Wang, Zhenguo,Chen, Yuzhi,Zhang, Xin...&Wang, Zhuo.(2019).Core-Shell Gold Nanorod@Layered Double Hydroxide Nanomaterial with Highly Efficient Photothermal Conversion and Its Application in Antibacterial and Tumor Therapy.ACS APPLIED MATERIALS & INTERFACES,11,(33)
MLA：
Ma, Kun,et al."Core-Shell Gold Nanorod@Layered Double Hydroxide Nanomaterial with Highly Efficient Photothermal Conversion and Its Application in Antibacterial and Tumor Therapy".ACS APPLIED MATERIALS & INTERFACES 11..33(2019):29630-29640
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