We report a strategy to synthesize materials in which POMs are enclosed in the cages of ZIFs. In three new compounds, H3PW12O40 subset of ZIF-8 (BIT-1), H4SiW12O40 subset of ZIF-8 (BIT-2) and H3PMo12O40 subset of ZIF-8 (BIT-3), different POM cages are 'trapped' inside the well-defined cages of ZIF-8 by one-pot mechanochemical synthesis. They show the highest capacity for methylene blue and controlled release of the anti-cancer agent 5-fluorouracil. BITs can be fully recovered and reused without losing their uptake capacity.
基金：
973 ProgramNational Basic Research Program of China [2013CB834704]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21231002, 21173021, 21276026, 21201018]; 111 ProjectMinistry of Education, China - 111 Project [B07012]; Program of Co-operation of the Beijing Education Commission [20091739006]
第一作者单位：[1]Beijing Inst Technol, Sch Chem, Minist Educ China, Key Lab Cluster Sci, Beijing 100081, Peoples R China
通讯作者：
通讯机构：[1]Beijing Inst Technol, Sch Chem, Minist Educ China, Key Lab Cluster Sci, Beijing 100081, Peoples R China[*1]Beijing Inst Technol, Sch Chem, Minist Educ China, Key Lab Cluster Sci, 5 South Zhongguancun St, Beijing 100081, Peoples R China
推荐引用方式(GB/T 7714)：
Li Rui,Ren Xiaoqian,Zhao Jingshu,et al.Polyoxometallates trapped in a zeolitic imidazolate framework leading to high uptake and selectivity of bioactive molecules[J].JOURNAL of MATERIALS CHEMISTRY a.2014,2(7):2168-2173.doi:10.1039/c3ta14267a.
APA：
Li, Rui,Ren, Xiaoqian,Zhao, Jingshu,Feng, Xiao,Jiang, Xin...&Wang, Bo.(2014).Polyoxometallates trapped in a zeolitic imidazolate framework leading to high uptake and selectivity of bioactive molecules.JOURNAL of MATERIALS CHEMISTRY a,2,(7)
MLA：
Li, Rui,et al."Polyoxometallates trapped in a zeolitic imidazolate framework leading to high uptake and selectivity of bioactive molecules".JOURNAL of MATERIALS CHEMISTRY a 2..7(2014):2168-2173
